Composition comprising a polyol, a sugar silicone surfactant and a oil-soluble polar modified polymer

ABSTRACT

The invention relates to a composition comprising a oil-soluble polar modified polymer, a sugar silicone surfactant and a hyperbranched polyol.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims the benefit of priority from U.S. ProvisionalApplication Ser. Nos. 61/221,351 and 61/221,303, both filed Jun. 29,2009, the entire contents of which are hereby incorporated by reference.

FIELD OF THE INVENTION

The present invention relates to a composition comprising at least onehyperbranched polyol having at least two hydroxyl groups, at least onesugar silicone surfactant and at least one oil-soluble polar modifiedpolymer. Such compositions have industrial, pharmacological and/orcosmetic applicability.

DISCUSSION OF THE BACKGROUND

U.S. Pat. No. 6,492,455 discloses water-soluble reaction products ofpolyamines and C6 olefin/maleic anhydride copolymers. Because thesecompositions are water-soluble, addition of water to such reactionproducts renders the products unsuitable for applications requiringwater-insolubility. For example, such reaction products are unsuitablefor use as a solid carrier containing colorant (for example, industrialpigments) or active agents (for example, pharmaceuticals) because thereaction product breaks down upon exposure to water.

Thus, there remains a need for improved products which can function as acarrier and/or matrix for desired agents.

SUMMARY OF THE INVENTION

The present invention relates to a composition comprising at least onepolyol having at least two hydroxyl groups, at least one sugar siliconesurfactant and at least one oil-soluble polar modified polymer.

The present invention also relates to compositions comprising at leastone polyol having at least two hydroxyl groups, at least one sugarsilicone surfactant, at least one oil-soluble polar modified polymer,and a desired agent such as a colorant or pharmacologically activeagent.

The present invention also relates to compositions, preferably solidcompositions, comprising at least one polyol having at least twohydroxyl groups, at least one sugar silicone surfactant, at least oneoil-soluble polar modified polymer, and water. Preferably, suchcompositions further comprise a desired agent.

The present invention also relates to compositions, preferably solidcompositions, comprising at least one polyol having at least twohydroxyl groups, at least one sugar silicone surfactant, at least oneoil-soluble polar modified polymer, and at least one oil. Preferably,such compositions further comprise a desired agent.

The present invention also relates to methods of treating, caring forand/or making up keratinous material (for example, skin, eyes, eyelashesor lips) by applying cosmetic compositions of the present invention tothe keratinous material in an amount sufficient to treat, care forand/or make up the keratinous material.

The present invention also relates to methods of improving the feel,shine and/or texture properties of a cosmetic composition uponapplication to a keratin material comprising forming a compositioncomprising at least one polyol having at least two hydroxyl groups, atleast one sugar silicone surfactant and at least one oil-soluble polarmodified polymer.

It is to be understood that both the foregoing general description andthe following detailed description are exemplary and explanatory only,and are not restrictive of the invention.

DETAILED DESCRIPTION OF THE INVENTION

As used herein, the expression “at least one” means one or more and thusincludes individual components as well as mixtures/combinations.

Other than in the operating examples, or where otherwise indicated, allnumbers expressing quantities of ingredients and/or reaction conditionsare to be understood as being modified in all instances by the term“about,” meaning within 10% to 15% of the indicated number.

“Film former” or “film forming agent” as used herein means a polymer orresin that leaves a film on the substrate to which it is applied, forexample, after a solvent accompanying the film former has evaporated,absorbed into and/or dissipated on the substrate.

“Transfer resistance” as used herein refers to the quality exhibited bycompositions that are not readily removed by contact with anothermaterial, such as, for example, a glass, an item of clothing or theskin, for example, when eating or drinking. Transfer resistance may beevaluated by any method known in the art for evaluating such. Forexample, transfer resistance of a composition may be evaluated by a“kiss” test. The “kiss” test may involve application of the compositionto human keratin material such as hair, skin or lips followed by rubbinga material, for example, a sheet of paper, against the hair, skin orlips after expiration of a certain amount of time following application,such as 2 minutes after application. Similarly, transfer resistance of acomposition may be evaluated by the amount of product transferred from awearer to any other substrate, such as transfer from the hair, skin orlips of an individual to a collar when putting on clothing after theexpiration of a certain amount of time following application of thecomposition to the hair, skin or lips. The amount of compositiontransferred to the substrate (e.g., collar, or paper) may then beevaluated and compared. For example, a composition may be transferresistant if a majority of the product is left on the wearer's hair,skin or lips. Further, the amount transferred may be compared with thattransferred by other compositions, such as commercially availablecompositions. In a preferred embodiment of the present invention, littleor no composition is transferred to the substrate from the hair, skin orlips.

“Long wear” compositions as used herein, refers to compositions wherecolor remains the same or substantially the same as at the time ofapplication, as viewed by the naked eye, after an extended period oftime. Long wear properties may be evaluated by any method known in theart for evaluating such properties. For example, long wear may beevaluated by a test involving the application of a composition to humanhair, skin or lips and evaluating the color of the composition after anextended period of time. For example, the color of a composition may beevaluated immediately following application to hair, skin or lips andthese characteristics may then be re-evaluated and compared after acertain amount of time. Further, these characteristics may be evaluatedwith respect to other compositions, such as commercially availablecompositions.

“Tackiness” as used herein refers to the adhesion between twosubstances. For example, the more tackiness there is between twosubstances, the more adhesion there is between the substances. Toquantify “tackiness,” it is useful to determine the “work of adhesion”as defined by IUPAC associated with the two substances. Generallyspeaking, the work of adhesion measures the amount of work necessary toseparate two substances. Thus, the greater the work of adhesionassociated with two substances, the greater the adhesion there isbetween the substances, meaning the greater the tackiness is between thetwo substances.

Work of adhesion and, thus, tackiness, can be quantified usingacceptable techniques and methods generally used to measure adhesion,and is typically reported in units of force time (for example, gramseconds (“g s”)). For example, the TA-XT2 from Stable Micro Systems,Ltd. can be used to determine adhesion following the procedures setforth in the TA-XT2 Application Study (ref: MATI/PO.25), revised January2000, the entire contents of which are hereby incorporated by reference.According to this method, desirable values for work of adhesion forsubstantially non-tacky substances include less than about 0.5 g s, lessthan about 0.4 g s, less than about 0.3 g s and less than about 0.2 g s.As known in the art, other similar methods can be used on other similaranalytical devices to determine adhesion.

“Waterproof” as used herein refers to the ability to repel water andpermanence with respect to water. Waterproof properties may be evaluatedby any method known in the art for evaluating such properties. Forexample, a mascara composition may be applied to false eyelashes, whichmay then be placed in water for a certain amount of time, such as, forexample, 20 minutes. Upon expiration of the pre-ascertained amount oftime, the false eyelashes may be removed from the water and passed overa material, such as, for example, a sheet of paper. The extent ofresidue left on the material may then be evaluated and compared withother compositions, such as, for example, commercially availablecompositions. Similarly, for example, a composition may be applied toskin, and the skin may be submerged in water for a certain amount oftime. The amount of composition remaining on the skin after thepre-ascertained amount of time may then be evaluated and compared. Forexample, a composition may be waterproof if a majority of the product isleft on the wearer, e.g., eyelashes, skin, etc. In a preferredembodiment of the present invention, little or no composition istransferred from the wearer.

“Substituted” as used herein, means comprising at least one substituent.Non-limiting examples of substituents include atoms, such as oxygenatoms and nitrogen atoms, as well as functional groups, such as hydroxylgroups, ether groups, alkoxy groups, acyloxyalky groups, oxyalkylenegroups, polyoxyalkylene groups, carboxylic acid groups, amine groups,acylamino groups, amide groups, halogen containing groups, ester groups,thiol groups, sulphonate groups, thiosulphate groups, siloxane groups,and polysiloxane groups. The substituent(s) may be further substituted.

“Volatile”, as used herein, means having a flash point of less thanabout 100° C.

“Non-volatile”, as used herein, means having a flash point of greaterthan about 100° C.

The compositions and methods of the present invention can comprise,consist of, or consist essentially of the essential elements andlimitations of the invention described herein, as well as any additionalor optional ingredients, components, or limitations described herein orotherwise useful.

In accordance with the present invention, the “hardness” of thecomposition may also be considered. The hardness of a composition may,for example, be expressed in gramforce (gf). The composition of thepresent invention may, for example, have a hardness ranging from 20 gfto 2000 gf, such as from 20 gf to 900 gf, and further such as from 20 gfto 600 gf, including all ranges and subranges therebetween.

This hardness is measured in one of two ways. A first test for hardnessis according to a method of penetrating a probe into the composition andin particular using a texture analyzer (for example TA-XT2i from Rheo)equipped with an ebonite cylinder of height 25 mm and diameter 8 mm. Thehardness measurement is carried out at 20° C. at the center of 5 samplesof the composition. The cylinder is introduced into each sample ofcomposition at a pre-speed of 2 mm/s and then at a speed of 0.5 mm/s andfinally at a post-speed of 2 mm/s, the total displacement being 1 mm.The recorded hardness value is that of the maximum peak observed. Themeasurement error is ±50 gf.

The second test for hardness is the “cheese wire” method, which involvescutting an 8.1 mm or preferably 12.7 mm in diameter stick compositionand measuring its hardness at 20° C. using a DFGHS 2 tensile testingmachine from Indelco-Chatillon Co. at a speed of 100 mm/minute. Thehardness value from this method is expressed in grams as the shear forcerequired to cut a stick under the above conditions. According to thismethod, the hardness of compositions according to the present inventionwhich may be in stick form may, for example, range from 30 gf to 300 gf,such as from 30 gf to 250 gf, for a sample of 8.1 mm in diameter stick,and further such as from 30 gf to 200 gf, and also further such as from30 gf to 120 gf for a sample of 12.7 mm in diameter stick.

The skilled artisan may choose to evaluate a composition using at leastone of the tests for hardness outlined above based on the applicationenvisaged and the hardness desired. If one obtains an acceptablehardness value, in view of the intended application, from at least oneof these hardness tests, the composition falls within preferredembodiments of the invention.

Oil-Soluble Polar Modified Polymer

According to the present invention, compositions comprising at least oneoil-soluble polar modified polymer are provided. “Polar modifiedpolymer” as used herein refers to a hydrophobic homopolymer or copolymerwhich has been modified with hydrophilic unit(s). “Oil-soluble” as usedherein means that the polar modified polymer is soluble in oil.

Suitable monomers for the hydrophobic homopolymers and/or copolymersinclude, but are not limited to, cyclic, linear or branched, substitutedor unsubstituted, C2-C20 compounds such as, for example, styrene,ethylene, propylene, isopropylene, butylene, isobutylene, pentene,isopentene, isoprene, hexene, isohexene, decene, isodecene, andoctadecene, including all ranges and subranges therebetween. Preferably,the monomers are C2-C8 compounds, more preferably C2-C6 compounds, andmost preferably C2-C4 compounds such as ethylene, propylene andbutylene.

Suitable hydrophilic unit(s) include, but are not limited to, maleicanhydride, acrylates, alkyl acrylates such as, for example, methylacrylate, ethyl acrylate, propyl acrylate, and butyl acrylate, andpolyvinylpyrrolidone (PVP).

According to the present invention, the polar modified polymer isoil-soluble: that is, the polymer does not contain a sufficient amountof hydrophilic unit(s) to render the entire polymer water-soluble oroil-insoluble. According to preferred embodiments, the polar modifiedpolymer contains the same amount of hydrophobic monomer as hydrophilicunit (1:1 ratio) or more hydrophobic monomer than hydrophilic unit.According to particularly preferred embodiments, the polar modifiedpolymer contains 50% or less hydrophilic unit(s) (based on weight of thepolymer), 40% or less hydrophilic unit(s), 30% or less hydrophilicunit(s), 20% or less hydrophilic unit(s), 10% or less hydrophilicunit(s), 5% or less hydrophilic unit(s), 4% or less hydrophilic unit(s),or 3% or less hydrophilic unit(s).

Preferably, the polar modified polymer has from about 0.5% to about 10%hydrophilic units, more preferably from about 1% to about 8% hydrophilicunits by weight with respect to the weight of the polymer, including allranges and subranges therebetween. Particularly preferredhydrophilically modified polymers are ethylene and/or propylenehomopolymers and copolymers which have been modified with maleicanhydride units.

According to preferred embodiments of the present invention, the polarmodified polymer is a wax. According to particularly preferredembodiments, the polar modified wax is made via metallocene catalysis,and includes polar groups or units as well as a hydrophobic backbone.Suitable modified waxes include those disclosed in U.S. patentapplication publication no. 20070031361, the entire contents of which ishereby incorporated by reference. Particularly preferred polar modifiedwaxes are C2-C3 polar modified waxes.

In accordance with preferred embodiments of the present invention, thepolar modified wax is based upon a homopolymer and/or copolymer wax ofhydrophobic monomers and has a weight-average molecular weight Mw ofless than or equal to 25 000 g/mol, preferably of 1000 to 22 000 g/moland particularly preferably of 4000 to 20,000 g/mol, a number-averagemolecular weight Mn of less than or equal to 15 000 g/mol, preferably of500 to 12 000 g/mol and particularly preferably of 1000 to 5000 g/mol, amolar mass distribution Mw/Mn in the range from 1.5 to 10, preferablyfrom 1.5 to 5, particularly preferably from 1.5 to 3 and especiallypreferably from 2 to 2.5, which have been obtained by metallocenecatalysis. Also, the polar modified wax preferably has a melting pointabove 75° C., more preferably above 90° C. such as, for example, amelting point between 90° C. and 160° C., preferably between 100° C. and150° C., including all ranges and subranges therebetween.

In the case of a copolymer wax, it is preferable to have, based on thetotal weight of the copolymer backbone, 0.1 to 30% by weight ofstructural units originating from the one monomer and 70.0 to 99.9% byweight of structural units originating from the other monomer. Suchhomopolymer and copolymer waxes can be made, for example, by the processdescribed in EP 571 882, the entire contents of which is herebyincorporated by reference, using the metallocene catalysts specifiedtherein. Suitable preparation processes include, for example, suspensionpolymerization, solution polymerization and gas-phase polymerization ofolefins in the presence of metallocene catalysts, with polymerization inthe monomers also being possible.

Polar modified waxes can be produced in a known manner from thehomopolymers and copolymers described above by oxidation withoxygen-containing gases, for example air, or by graft reaction withpolar monomers, for example maleic acid or acrylic acid or derivativesof these acids. The polar modification of metallocene polyolefin waxesby oxidation with air is described, for example, in EP 0 890 583 A1, andthe modification by grafting is described, for example, in U.S. Pat. No.5,998,547, the entire contents of both of which are hereby incorporatedby reference in their entirety.

Acceptable polar modified waxes include, but are not limited to,homopolymers and/or copolymers of ethylene and/or propylene groups whichhave been modified with hydrophilic units such as, for example, maleicanhydride, acrylate, methacrylate, polyvinylpyrrolidone (PVP), etc.Preferably, the C2-C3 wax has from about 0.5% to about 10% hydrophilicunits, more preferably from about 1% to about 8% hydrophilic units byweight with respect to the weight of the wax, including all ranges andsubranges therebetween. Particularly preferred hydrophilically modifiedwaxes are ethylene and/or propylene homopolymers and copolymers whichhave been modified with maleic anhydride units.

Particularly preferred C2-C3 polar modified waxes for use in the presentinvention are polypropylene and/or polyethylene-maleic anhydridemodified waxes (“PEMA,” “PPMA.” “PEPPMA”) commercially available fromClariant under the trade name LICOCARE or LICOCENE, Specific examples ofsuch waxes include products marketed by Clariant under the LicoCare namehaving designations such as PP207.

Other suitable polar modified polymers include, but are not limited toA-C 573 A (ETHYLENE-MALEIC ANHYDRIDE COPOLYMER; Drop Point, Mettler:106° C.) from Honeywell, A-C 596 A (PROPYLENE-MALEIC ANHYDRIDECOPOLYMER; Drop Point, Mettler: 143° C.) from Honeywell, A-C 597(PROPYLENE-MALEIC ANHYDRIDE COPOLYMER; Drop Point, Mettler: 141° C.)from Honeywell, ZeMac® copolymers (from VERTELLUS) which are 1:1copolymers of ethylene and maleic anhydride, polyisobutylene-maleicanhydride sold under the trade name ISOBAM (from Kuraray),polyisoprene-graft-maleic anhydride sold by Sigma Aldrich, poly(maleicanhydride-octadecene) sold by Chevron Philips Chemical Co., poly(ethylene-co-butyl acrylate-co-maleic anhydride) sold under the tradename of Lotader (e.g. 2210, 3210, 4210, and 3410 grades) by Arkema,copolymers in which the butyl acrylate is replaced by other alkylacrylates (including methyl acrylate [grades 3430, 4404, and 4503] andethyl acrylate [grades 6200, 8200, 3300, TX 8030, 7500, 5500, 4700, and4720) also sold by Arkema under the Lotader name, and isobutylene maleicanhydride copolymer sold under the name ACO-5013 by ISP.

According to other embodiments of the present invention, the polarmodified polymer is not a wax. In accordance with these embodiments ofthe present invention, the polar modified polymer is based upon ahomopolymer and/or copolymer of hydrophobic monomer(s) and has aweight-average molecular weight Mw of less than or equal to 1,000,000g/mol, preferably of 1000 to 250,000 g/mol and particularly preferablyof 5,000 to 50,000 g/mol, including all ranges and subrangestherebetween.

In accordance with these embodiments, the polar modified polymer can beof any form typically associated with polymers such as, for example,block copolymer, a grafted copolymer or an alternating copolymer. Forexample, the polar modified polymer can contain a hydrophobic backbone(such as polypropylene and/or polyethylene) onto which hydrophilicgroups (such as maleic anhydride) have been attached by any meansincluding, for example, grafting. The attached groups can have anyorientation (for example, atactic, isotactic or syndiotactic along thebackbone).

Preferably, the oil soluble polar modified polymer(s) represent fromabout 1% to about 30% of the total weight of the composition, morepreferably from about 2.5% to about 15% of the total weight of thecomposition, and most preferably from about 5% to about 10%, includingall ranges and subranges therebetween.

Hyperbranched Polyol Compound

According to the present invention, compositions comprising at least onehyperbranched polyol compound are provided. In accordance with thepresent invention, the hyperbranched polyol compound has at least twohydroxyl groups available to react with hydrophilic groups on thebackbone of the polar modified wax.

“Hydroxyl number” or “hydroxyl value” which is sometimes also referredto as “acetyl value” is a number which indicates the extent to which asubstance may be acetylated; it is the number of milligrams of potassiumhydroxide required for neutralization of the acetic acid liberated onsaponifying 1 g of acetylated sample. According to preferredembodiments, the at least one hyperbranched polyol has a hydroxyl numberbetween 50 and 250, preferably between 75 and 225, preferably between100 and 200, preferably between 125 and 175, including all ranges andsubranges therebetween such as 90 to 150.

In accordance with the present invention, “hyperbranched polyol” refersto dendrimers, hyperbranched macromolecules and other dendron-basedarchitectures. Hyperbranched polyols can generally be described asthree-dimensional highly branched molecules having a tree-likestructure. They are characterized by a great number of end groups, atleast two of which are hydroxyl groups. The dendritic or “tree-like”structure preferably shows regular symmetric branching from a centralmultifunctional core molecule leading to a compact globular orquasi-globular structure with a large number of end groups per molecule.Suitable examples of hyperbranched polyols can be found in U.S. Pat. No.7,423,104, and U.S. patent applications 2008/0207871 and 2008/0286152,the entire contents of all of which are hereby incorporated byreference. Other suitable examples include alcohol functional olefinicpolymers such as those available from New Phase Technologies.

Dendrimers tend to be exact, monodisperse structures built layerwise (ingenerations) around a core moiety, with a polymer branching point inevery repeating unit. Hyperbranched polymers tend to possess a number ofcharacteristics which are similar to dendrimers but they tend to bepolydispersed and contain relatively linear segments off of which aplurality of highly branched segments are grown or attached.

Furthermore, “hyperbranched polymers” refers to polymers comprising atleast two, for example three, polymeric branches, forming either themain branch or a secondary branch, and each comprising at least one atleast trifunctional branch point, which may be identical or different,and which is able to form at least two at least trifunctional branchpoints, different from and independent of one another. Each branch pointmay be, for example, arranged in the interior of at least one chain. Thebranches may be, for example, connected to one another by apolyfunctional compound.

As used herein, “trifunctional branch point” means the junction pointbetween three polymer branches, of which at least two branches may bedifferent in chemical constitution and/or structure. For example,certain branches may be hydrophilic, i.e. may predominantly containhydrophilic monomers, and other branches may be hydrophobic, i.e., maypredominantly contain hydrophobic monomers. Further branches mayadditionally form a random polymer or a block polymer.

As used herein, “at least trifunctional branch” means the junctionpoints between at least three polymeric branches, for example npolymeric branches, of which n−1 branches at least are different inchemical constitution and/or structure.

As used herein, “chain interior” means the atoms situated within thepolymeric chain, to the exclusion of the atoms forming the two ends ofthis chain.

As used herein, “main branch” means the branch or polymeric sequencecomprising the greatest percentage by weight of monomer(s).

Branches which are not main branches are called “secondary branches”.

According to particularly preferred embodiments of the presentinvention, the hyperbranched polyol comprises a hydrophobic chaininterior. Preferably, the chain interior comprises one or morehydrocarbon groups, one or more silicon-based groups, or mixturesthereof. Particularly preferred chain interiors comprise olefinicpolymers or copolymers and/or silicone polymers or copolymers.

Suitable olefinic monomers include, but are not limited to, compoundshaving from about 2 to about 30 carbon atoms per molecule and having atleast one olefinic double bond which are acyclic, cyclic, polycyclic,terminal α, internal, linear, branched, substituted, unsubstituted,functionalized, and/or non-functionalized. For example, suitablemonomers include ethylene, propylene, 1-butene, 2-butene,3-methyl-1-butene, and isobutylene.

Suitable silicone groups for inclusion into the interior chain include“D” groups (for example, dimethicone or substituted dimethicone groups).

An exemplary structure is as follows:

Where X corresponds to hydroxyl functionality and R corresponds to amethyl group or an alkyl group preferably containing 2-30 atoms.

According to preferred embodiments, the at least one hyperbranchedpolyol has a molecular weight (Mw) between about 3,000 and 25,000,preferably between 4,000 and 22,000, preferably between 5,000 and20,000, including all ranges and subranges therebetween such as 4000 to5500.

According to preferred embodiments, the at least one hyperbranchedpolyol has a viscosity at 90° F. of between 1,000 and 8,000 centipoise(cps), preferably 2,000 and 7,000 cps, and preferably 3,000 and 6,000cps, including all ranges and subranges therebetween.

According to preferred embodiments, the at least one hyperbranchedpolyol is present in the composition of the present invention in anamount ranging from about 0.1 to about 15% by weight, more preferablyfrom about 1 to about 10% by weight, most preferably from about 2 toabout 8% by weight, based on the total weight of the composition,including all ranges and subranges within these ranges.

Preferably, the weight ratio of polyol to oil-soluble polar modifiedpolymer is between 4:1 and 1:4, preferably between 3:1 and 1:3, andpreferably between 2:1 and 1:2, including all ranges and subrangestherebetween.

According to preferred embodiments, the oil-soluble polar modifiedpolymer is in an oil carrier, and the polyol is blended into the oilcarrier during production of the compositions of the present invention.Because the oil-soluble polar modified polymer is typically solid atroom temperature, the oil carrier is preferably heated to liquefy thewax prior to combination with the polyol. Preferably, the oil carrier isheated beyond the melting point of the Oil-soluble polar modifiedpolymer, typically up to about 70° C., 80° C., 90° C., 100° C. or 110°C. Then, the polar modified wax is preferably combined with the polyolthrough blending at room temperature or at a slightly elevatedtemperature (that is, at a temperature between room temperature and thetemperature at which the polar modified wax was liquefied or melted)such as, for example, about 30° C., 40° C., 50° C., 60° C. or 70° C.,for at least about 30 minutes.

According to some embodiments of the present invention, the polyol canbe in an aqueous carrier, and the polar modified wax can be combinedwith the polyol by combining the oil carrier with the aqueous carrier.According to other embodiments, the polyol does not have to be in anaqueous carrier—the polyol can be added to the oil carrier first, andthen water can be subsequently added to the mixture.

According to preferred embodiments, the oil carrier comprises volatileand/or non-volatile oils. Such oils can be any acceptable oil includingbut not limited to silicone oils and/or hydrocarbon oils.

According to preferred embodiments, the oil carrier comprises one ormore volatile silicone oils. Examples of such volatile silicone oilsinclude linear or cyclic silicone oils having a viscosity at roomtemperature less than or equal to 6 cSt and having from 2 to 7 siliconatoms, these silicones being optionally substituted with alkyl or alkoxygroups of 1 to 10 carbon atoms. Specific oils that may be used in theinvention include octamethyltetrasiloxane, decamethylcyclopentasiloxane,dodecamethylcyclohexasiloxane, heptamethyloctyltrisiloxane,hexamethyldisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxaneand their mixtures. Other volatile oils which may be used include KF 96Aof 6 cSt viscosity, a commercial product from Shin Etsu having a flashpoint of 94° C. Preferably, the volatile silicone oils have a flashpoint of at least 40° C.

Non-limiting examples of volatile silicone oils are listed in Table 1below.

TABLE 1 Flash Point Viscosity Compound (° C.) (cSt) Octyltrimethicone 931.2 Hexyltrimethicone 79 1.2 Decamethylcyclopentasiloxane 72 4.2(cyclopentasiloxane or D5) Octamethylcyclotetrasiloxane 55 2.5(cyclotetradimethylsiloxane or D4) Dodecamethylcyclohexasiloxane (D6) 937 Decamethyltetrasiloxane (L4) 63 1.7 KF-96 A from Shin Etsu 94 6 PDMS(polydimethylsiloxane) DC 200 56 1.5 (1.5 cSt) from Dow Corning PDMS DC200 (2 cSt) from Dow Corning 87 2

Further, a volatile linear silicone oil may be employed in the presentinvention. Suitable volatile linear silicone oils include thosedescribed in U.S. Pat. No. 6,338,839 and WO03/042221, the contents ofwhich are incorporated herein by reference. In one embodiment thevolatile linear silicone oil is decamethyltetrasiloxane. In anotherembodiment, the decamethyltetrasiloxane is further combined with anothersolvent that is more volatile than decamethyltetrasiloxane.

According to other preferred embodiments, the oil carrier comprises oneor more non-silicone volatile oils and may be selected from volatilehydrocarbon oils, volatile esters and volatile ethers. Examples of suchvolatile non-silicone oils include, but are not limited to, volatilehydrocarbon oils having from 8 to 16 carbon atoms and their mixtures andin particular branched C8 to C16 alkanes such as C8 to C16 isoalkanes(also known as isoparaffins), isododecane, isodecane, and for example,the oils sold under the trade names of Isopar or Permethyl. Preferably,the volatile non-silicone oils have a flash point of at least 40° C.

Non-limiting examples of volatile non-silicone volatile oils are givenin Table 2 below.

TABLE 2 Compound Flash Point (° C.) Isododecane 43 Propylene glycoln-butyl ether 60 Ethyl 3-ethoxypropionate 58 Propylene glycolmethylether acetate 46 Isopar L (isoparaffin C11-C13) 62 Isopar H(isoparaffin C11-C12) 56

The volatility of the solvents/oils can be determined using theevaporation speed as set forth in U.S. Pat. No. 6,338,839, the contentsof which are incorporated by reference herein.

According to preferred embodiments of the present invention, the oilcarrier comprises at least one non-volatile oil. Examples ofnon-volatile oils that may be used in the present invention include, butare not limited to, polar oils such as:

-   -   hydrocarbon-based plant oils with a high triglyceride content        consisting of fatty acid esters of glycerol, the fatty acids of        which may have varied chain lengths, these chains possibly being        linear or branched, and saturated or unsaturated; these oils are        especially wheat germ oil, corn oil, sunflower oil, karite        butter, castor oil, sweet almond oil, macadamia oil, apricot        oil, soybean oil, rapeseed oil, cottonseed oil, alfalfa oil,        poppy oil, pumpkin oil, sesame seed oil, marrow oil, avocado        oil, hazelnut oil, grape seed oil, blackcurrant seed oil,        evening primrose oil, millet oil, barley oil, quinoa oil, olive        oil, rye oil, safflower oil, candlenut oil, passion flower oil        or musk rose oil; or caprylic/capric acid triglycerides, for        instance those sold by the company Stearineries Dubois or those        sold under the names Miglyol 810, 812 and 818 by the company        Dynamit Nobel;    -   synthetic oils or esters of formula R5COOR6 in which R5        represents a linear or branched higher fatty acid residue        containing from 1 to 40 carbon atoms, including from 7 to 19        carbon atoms, and R6 represents a branched hydrocarbon-based        chain containing from 1 to 40 carbon atoms, including from 3 to        20 carbon atoms, with R6+R≧10, such as, for example, Purcellin        oil (cetostearyl octanoate), isononyl isononanoate, C12 to C15        alkyl benzoate, isopropyl myristate, 2-ethylhexyl palmitate, and        octanoates, decanoates or ricinoleates of alcohols or of        polyalcohols; hydroxylated esters, for instance isostearyl        lactate or diisostearyl malate; and pentaerythritol esters;    -   synthetic ethers containing from 10 to 40 carbon atoms;    -   C8 to C26 fatty alcohols, for instance oleyl alcohol; and    -   mixtures thereof.

Further, examples of non-volatile oils that may be used in the presentinvention include, but are not limited to, non-polar oils such asbranched and unbranched hydrocarbons and hydrocarbon waxes includingpolyolefins, in particular Vaseline (petrolatum), paraffin oil,squalane, squalene, hydrogenated polyisobutene, hydrogenated polydecene,polybutene, mineral oil, pentahydrosqualene, and mixtures thereof.

Sugar Silicone Surfactant

According to the present invention, compositions comprising at least onesugar silicone surfactant are provided. The sugar silicone surfactant ofthe present invention has the following formula:Sach-X-Dn-X-Sach

where Sach represents a saccharide moiety containing multiple hydroxylgroups. Suitable saccharide moieties include, but are not limited to,those based on monosaccharides such as, for example, glucose, fructose,galactose, ribose, mannose, sorbose, etc., and those based oneoligosaccharides such as, for example, sucrose, lactose, palatinose,raffinose, lactosucrose, glucosylsucrose, galactosyl-sucrose, xylobiose,etc. Preferably, the saccharide moiety is based on a monosaccharide,most preferably glucose;

X represents a linear or branched, saturated or unsaturated, C1 to C40hydrocarbon-based group, possibly containing in their chain one or moreoxygen, sulphur and/or nitrogen atoms. Preferably, X represents alinear, unsubstituted alkyl group containing at least one N atom, mostpreferably a linear, unsubstituted alkyl group having 1-6 carbon atomsand at least one N atom;

D represents a silicone based group of the formula R2SiO, where R2represents a linear or branched, saturated or unsaturated, C1 to C10hydrocarbon-based group. Preferably, R2 is an unsubstituted C1 to C3alkyl group (methyl, ethyl, propyl), most preferably a methyl group; and

n represents a number between 1 and 1000, preferably between 100 and500, more preferably between 250 and 400, and more preferably between300 and 350, including all ranges and subranges therebetween.

Preferably, such sugar silicone surfactants are prepared by reacting alactone form of the saccharide with an amino form of the D group,thereby forming an alkyl group X having an N atom between the saccharidemoiety and the silicone moiety.

Particularly preferred sugar silicone surfactants includegluconamidoethylaminopropylsilicone, lactobionolactonesiloxane, or amixture thereof.

Preferably, the sugar silicone surfactant represents from about 0.5% toabout 25% of the total weight of the composition, more preferably fromabout 0.75% to about 15% of the total weight of the composition, andmost preferably from about 1% to about 10%, including all ranges andsubranges therebetween.

Alcohol

According to the preferred embodiments of the present invention,compositions of the present invention may further comprise at least onealcohol. The alcohol may be either liner or branched. Preferably, thealcohol is non-volatile, having an elevated boiling point. For example,the alcohol has a boiling point of at least 50° C., 75° C., or 100° C.Also preferably, the alcohol has at least 8 carbon atoms, preferably atleast 10 carbon atoms. Suitable examples of acceptable alcohols includebutyl octanol, butyl nonanol, butyl decanol, pentyl octanol, pentylnonanol, pentyl decanol, hexyl octanol, hexyl nonanol, and hexyldecanol.

Preferably, the alcohol(s) represent from about 0.1% to about 30% of thetotal weight of the composition, more preferably from about 0.5% toabout 15% of the total weight of the composition, and most preferablyfrom about 1% to about 10%, including all ranges and subrangestherebetween.

According to particularly preferred embodiments of the presentinvention, the alcohol, the alkoxylated surfactant having at least 8carbon atoms and at least two alkoxylation units, and the sugar siliconesurfactant are combined to form an emulsion. A suitable example of suchan emulsion is the product sold by Dow Corning under the designationCE-8810 (gluconamidoethylaminopropylsilicone/C11-C15Pareth-40/butyloctanol).

Gelling Agent

According to the present invention, the compositions may optionallyfurther comprise at least one gelling agent chosen from cellulose, andderivates thereof are provided. Such gelling agents are typically foundin the aqueous phase of a composition.

Examples of suitable cellulose, and derivatives thereof include, but arenot limited to:

cellulose polymers such as hydroxyethylcellulose,hydroxypropylcellulose, methylcellulose, ethylhydroxyethylcellulose,carboxymethylcellulose, and quaternized cellulose derivatives;

cellulosic thickeners, for example, hydroxyethylcellulose,hydroxypropylcellulose, and carboxymethylcellulose, guar gum and itsderivatives, such as hydroxypropylguar, gums of microbial origin, suchas xanthan gum and scleroglucan gum;

quaternized cellulose derivatives and polyacrylates containingnon-cyclic amine side groups. The quaternized cellulose derivatives mayinclude, for example:

quaternized celluloses modified with groups comprising at least onefatty chain, such as alkyl, arylalkyl, and alkylaryl groups comprisingat least 8 carbon atoms, and mixtures thereof;

quaternized hydroxyethylcelluloses modified with groups comprising atleast one fatty chain, such as alkyl, arylalkyl, and alkylaryl groupscomprising at least 8 carbon atoms, and mixtures thereof;

polyquaternium-37 (commercially available from Cognis under thetrademark name Ultragel 300 and from Ciba under the trademark nameSalCARE); hydroxyalkyl cellulose polymers and alkyl hydroxyalkylcellulose polymers such as hydroxyethyl cellulose (commerciallyavailable from Amerchol and The Dow Chemical Company and Hercules underthe tradenames Cellosize and Natrosol), hydroxypropyl cellulose(commercially available from Hercules under the tradename Klucel) andcetyl hydroxyethyl cellulose (commercially available from Hercules underthe tradename Natrosol);

carboxymethyl cellulose (commercially available from Hercules under thetradename Aqualon), natural or synthetic gums, and starches;

quaternized alkylhydroxyethylcelluloses containing C8-C30 fatty chainsinclude, for instance, the products Quatrisoft LM 200, Quatrisoft LM-X529-18-A, Quatrisoft LM-X 529-18B (C12 alkyl), and Quatrisoft LM-X 529-8(C18 alkyl) sold by the company Amerchol, and the products Crodacel QM,Crodacel QL (C12 alkyl) and Crodacel QS (C18 alkyl) sold by the companyCroda.

Particularly preferred thickening agents are polysaccharides orpolysaccharide derivatives such as hydroxyethyl cellulose, hydroxypropylcellulose, methyl cellulose, xanthan gum, guar gum,hydroxymethylcellulose derivatives such as hydroxypropyl methylcelluloseand hydroxybutyl methyl cellulose, starch and starch derivatives.

Particularly preferred rheology-modifying agents are cetyl hydroxyethylcellulose, quaternized celluloses and hydroxyethylcelluloses.

Preferably, the gelling agent is present in the composition of thepresent invention in an amount ranging from about 0.1% to about 10.0% byweight, preferably from about 0.5% to about 5.0% by weight, preferablyfrom about 1.0% to about 4.0% by weight of the total weight of thecomposition, including all ranges and subranges therebetween.

It may be desirable to employ an additional gelling agent, other thancellulose and derivatives thereof. Examples of such other gelling agentsinclude:

water-soluble gelling polymers such as:

proteins, such as proteins of plant origin, for instance wheat proteinsand soy proteins; proteins of animal origin such as keratins, forexample keratin hydrolysates and sulphonic keratins;

anionic, cationic, amphoteric or nonionic chitin or chitosan polymers;and

synthetic thickeners such as crosslinked homopolymers of acrylic acidand of acrylamidopropanesulphonic acid;

fatty acid amides such as coconut diethanolamide and monoethanolamide,and oxyethylenated monoethanolamide of carboxylic acid alkyl ether, andassociative polymers.

Cationic associative polymers may include, but are not limited to:

cationic associative polyurethanes which may be formed fromdiisocyanates and from various compounds with functions containing alabile hydrogen. The functions containing a labile hydrogen may bechosen from alcohol, primary and secondary amine, and thiol functions,giving, after reaction with the diisocyanate functions, polyurethanes,polyureas, and polythioureas, respectively. The expression“polyurethanes which can be used according to the present invention”encompasses these three types of polymer, namely polyurethanes per se,polyureas and polythioureas, and also copolymers thereof. Example ofsuch compounds include, but are not limited to, methylenediphenyldiisocyanate, methylenecyclohexane diisocyanate, isophoronediisocyanate, tolylene diisocyanate, naphthalene diisocyanate, butanediisocyanate, and hexane diisocyanate; and

carboxyvinyl polymers, acrylic acid/polyallyl sucrose copolymers,polyacrylic compounds and acrylic acid/ethyl acrylate copolymers(commercially available under the CARBOPOL tradenames).

If present, such other gelling agent is preferably present in thecomposition of the present invention in an amount ranging from about0.1% to about 10.0% by weight, preferably from about 0.5% to about 5.0%by weight, preferably from about 1.0% to about 4.0% by weight of thetotal weight of the composition.

According to preferred embodiments of the present invention, a desiredagent can be incorporated within the composition. The desired agent canbe, for example, any colorant (pigment, dye, etc.), any pharmaceuticallyor cosmetically active agent, or any film forming agent known in theart. Such a desired agent can be incorporated into the composition ofthe present invention and can be active during subsequent use of thecomposition. For example, a cosmetic makeup composition or a paintcomposition comprising colorant can provide colorant and/or film formingagent to a substrate (skin, lips, wall, frame, etc.) during use toprovide the substrate with the desired film and/or color. Similarly, apharmaceutical or cosmetic composition comprising a pharmaceuticallyactive agent can provide such active agent to the patient or consumerupon use (for example, a transdermal patch within which is apharmaceutically or cosmetically active agent, or a tablet or capsulecontaining the active agent).

Acceptable colorants include pigments, dyes, such as liposoluble dyes,nacreous pigments, and pearling agents.

Representative liposoluble dyes which may be used according to thepresent invention include Sudan Red, DC Red 17, DC Green 6, β-carotene,soybean oil, Sudan Brown, DC Yellow 11, DC Violet 2, DC Orange 5,annatto, and quinoline yellow.

Representative nacreous pigments include white nacreous pigments such asmica coated with titanium or with bismuth oxychloride, colored nacreouspigments such as titanium mica with iron oxides, titanium mica withferric blue or chromium oxide, titanium mica with an organic pigmentchosen from those mentioned above, and nacreous pigments based onbismuth oxychloride.

Representative pigments include white, colored, inorganic, organic,polymeric, nonpolymeric, coated and uncoated pigments. Representativeexamples of mineral pigments include titanium dioxide, optionallysurface-treated, zirconium oxide, zinc oxide, cerium oxide, iron oxides,chromium oxides, manganese violet, ultramarine blue, chromium hydrate,and ferric blue. Representative examples of organic pigments includecarbon black, pigments of D & C type, and lakes based on cochinealcarmine, barium,

Acceptable film forming agents and/or rheological agents are known inthe art and include, but are not limited to, those disclosed in U.S.patent application publication no. 2004/0170586, the entire contents ofwhich is hereby incorporated by reference.

Non-limiting representative examples of acceptable filmforming/rheological agents include silicone resins such as, for example,MQ resins (for example, trimethylsiloxysilicates), T-propylsilsesquioxanes and MK resins (for example, polymethylsilsesquioxanes),silicone esters such as those disclosed in U.S. Pat. Nos. 6,045,782,5,334,737, and 4,725,658, the disclosures of which are herebyincorporated by reference, polymers comprising a backbone chosen fromvinyl polymers, methacrylic polymers, and acrylic polymers and at leastone chain chosen from pendant siloxane groups and pendant fluorochemicalgroups such as those disclosed in U.S. Pat. Nos. 5,209,924, 4,693,935,4,981,903, 4,981,902, and 4,972,037, and WO 01/32737, the disclosures ofwhich are hereby incorporated by reference, polymers such as thosedescribed in U.S. Pat. No. 5,468,477, the disclosure of which is herebyincorporated by reference (a non-limiting example of such polymers ispoly(dimethylsiloxane)-g-poly(isobutyl methacrylate), which iscommercially available from 3M Company under the tradename VS 70 IBM).

Suitable examples of acceptable liposoluble polymers include, but arenot limited to, polyalkylenes, polyvinylpyrrolidone (PVP) orvinylpyrrolidone (VP) homopolymers or copolymers, copolymers of a C2 toC30, such as C3 to C22 alkene, and combinations thereof. As specificexamples of VP copolymers which can be used in the invention, mentionmay be made of VP/vinyl acetate, VP/ethyl methacrylate, butylatedpolyvinylpyrrolidone (PVP), VP/ethyl methacrylate/methacrylic acid,VP/eicosene, VP/hexadecene, VP/triacontene, VP/styrene or VP/acrylicacid/lauryl methacrylate copolymer.

One type of block copolymer which may be employed in the compositions ofthe present invention is a thermoplastic elastomer. The hard segments ofthe thermoplastic elastomer typically comprise vinyl monomers in varyingamounts. Examples of suitable vinyl monomers include, but are notlimited to, styrene, methacrylate, acrylate, vinyl ester, vinyl ether,vinyl acetate, and the like.

The soft segments of the thermoplastic elastomer typically compriseolefin polymers and/or copolymers which may be saturated, unsaturated,or combinations thereof. Suitable olefin copolymers may include, but arenot limited to, ethylene/propylene copolymers, ethylene/butylenecopolymers, propylene/butylene copolymers, polybutylene, polyisoprene,polymers of hydrogenated butanes and isoprenes, and mixtures thereof.

Thermoplastic elastomers useful in the present invention include blockcopolymers e.g., di-block, tri-block, multi-block, radial and star blockcopolymers, and mixtures and blends thereof. A di-block thermoplasticelastomer is usually defined as an A-B type or a hard segment (A)followed by a soft segment (B) in sequence. A tri-block is usuallydefined as an A-B-A type copolymer or a ratio of one hard, one soft, andone hard segment. Multi-block or radial block or star blockthermoplastic elastomers usually contain any combination of hard andsoft segments, provided that the elastomers possess both hard and softcharacteristics.

In preferred embodiments, the thermoplastic elastomer of the presentinvention may be chosen from the class of Kraton™ rubbers (ShellChemical Company) or from similar thermoplastic elastomers. Kraton™rubbers are thermoplastic elastomers in which the polymer chainscomprise a di-block, tri-block, multi-block or radial or star blockconfiguration or numerous mixtures thereof. The Kraton™ tri-blockrubbers have polystyrene (hard) segments on each end of a rubber (soft)segment, while the Kraton™ di-block rubbers have a polystyrene (hard)segment attached to a rubber (soft) segment. The Kraton™ radial or starconfiguration may be a four-point or other multipoint star made ofrubber with a polystyrene segment attached to each end of a rubbersegment. The configuration of each of the Kraton™ rubbers forms separatepolystyrene and rubber domains.

Each molecule of Kraton™ rubber is said to comprise block segments ofstyrene monomer units and rubber monomer and/or co-monomer units. Themost common structure for the Kraton™ triblock copolymer is the linearA-B-A block type styrene-butadiene-styrene, styrene-isoprene-styrene,styrene-ethylenepropylene-styrene, or styrene-ethylenebutylene-styrene.The Kraton™ di-block is preferably the AB block type such asstyrene-ethylenepropylene, styrene-ethylenebutylene, styrene-butadiene,or styrene-isoprene. The Kraton™ rubber configuration is well known inthe art and any block copolymer elastomer with a similar configurationis within the practice of the invention. Other block copolymers are soldunder the tradename Septon (which represent elastomers known as SEEPS,sold by Kurary, Co., Ltd) and those sold by Exxon Dow under thetradename Vector™.

Other thermoplastic elastomers useful in the present invention includethose block copolymer elastomers comprising astyrene-butylene/ethylene-styrene copolymer (tri-block), anethylene/propylene-styrene copolymer (radial or star block) or a mixtureor blend of the two. (Some manufacturers refer to block copolymers ashydrogenated block copolymers, e.g. hydrogenatedstyrene-butylene/ethylene-styrene copolymer (tri-block)).

Acceptable film forming/rheological agents also include water solublepolymers such as, for example, high molecular weight crosslinkedhomopolymers of acrylic acid, and Acrylates/C10-30 Alkyl AcrylateCrosspolymer, such as the Carbopol® and Pemulen®; anionic acrylatepolymers such as Salcare® AST and cationic acrylate polymers such asSalcare® SC96; acrylamidopropylttrimonium chloride/acrylamide;hydroxyethyl methacrylate polymers, Steareth-10 Allyl Ether/AcrylateCopolymer; Acrylates/Beheneth-25 Metacrylate Copolymer, known as Aculyn®28; glyceryl polymethacrylate, Acrylates/Steareth-20 MethacrylateCopolymer; bentonite; gums such as alginates, carageenans, gum acacia,gum arabic, gum ghatti, gum karaya, gum tragacanth, guar gum; guarhydroxypropyltrimonium chloride, xanthan gum or gellan gum; cellulosederivatives such as sodium carboxymethyl cellulose, hydroxyethylcellulose, hydroxymethyl carboxyethyl cellulose, hydroxymethylcarboxypropyl cellulose, ethyl cellulose, sulfated cellulose,hydroxypropyl cellulose, methyl cellulose, hydroxypropylmethylcellulose, microcrystalline cellulose; agar; pectin; gelatin; starch andits derivatives; chitosan and its derivatives such as hydroxyethylchitosan; polyvinyl alcohol, PVM/MA copolymer, PVM/MA decadienecrosspolymer, poly(ethylene oxide) based thickeners, sodium carbomer,and mixtures thereof.

According to preferred embodiments of the present invention,compositions of the present invention can comprise substantial amountsof water. Preferably, compositions of the present invention comprisefrom about 5% to about 50% water, more preferably from about 15% toabout 45% water, and more preferably from about 25% to about 40% waterby weight with respect to the total weight of the composition, includingall ranges and subranges therebetween. According to particularlypreferred embodiments, compositions of the present invention and atleast 25% water are solid compositions. Such solid compositions arepreferably in the form of a stick (for example, a lipstick or a stickfoundation).

Compositions of the present invention can optionally further compriseany additive usually used in the field(s) under consideration. Forexample, dispersants such as poly(12-hydroxystearic acid), antioxidants,essential oils, sunscreens, preserving agents, fragrances, fillers,neutralizing agents, cosmetic and dermatological active agents such as,for example, emollients, moisturizers, vitamins, essential fatty acids,surfactants, silicone elastomers, pasty compounds, viscosity increasingagents such as waxes or liposoluble/lipodispersible polymers, andmixtures thereof can be added. A non-exhaustive listing of suchingredients can be found in U.S. patent application publication no.2004/0170586, the entire contents of which are hereby incorporated byreference. Further examples of suitable additional components can befound in the other references which have been incorporated by referencein this application. Still further examples of such additionalingredients may be found in the International Cosmetic IngredientDictionary and Handbook (9th ed. 2002).

In one embodiment of the present invention, the compositions of thepresent invention are substantially free of silicone oils (i.e., containless than about 0.5% silicone oils). In another embodiment, thecompositions are substantially free of non-silicone oils (i.e., containless than about 0.5% non-silicone oils). In another embodiment, thecompositions are substantially free of non-volatile oils (i.e., containless than about 0.5% non-volatile oils).

Another particularly preferred embodiment of the present invention is acomposition which contains so little elastomer that the presence of suchelastomer not affect the cosmetic properties of the composition.Preferably, the compositions are substantially free of such elastomers(i.e., contain less than about 0.5% elastomer), essentially free of suchelastomers (i.e., contain less than about 0.25% elastomer) or free ofsuch elastomer (i.e., contain no elastomer).

According to other preferred embodiments, methods of treating, caringfor and/or enhancing the appearance of keratinous material by applyingcompositions of the present invention to the keratinous material in anamount sufficient to treat, care for and/or enhance the appearance ofthe keratinous material are provided. In accordance with these precedingpreferred embodiments, the compositions of the present inventioncomprising at least one polar modified wax, at least one sugar siliconesurfactant and at least one polyol compound are applied topically to thedesired area of the keratin material in an amount sufficient to treat,care for and/or enhance the appearance of the keratinous material. Thecompositions may be applied to the desired area as needed, preferablyonce or twice daily, more preferably once daily and then preferablyallowed to dry before subjecting to contact such as with clothing orother objects (for example, a glass or a topcoat). Preferably, thecomposition is allowed to dry for about 1 minute or less, morepreferably for about 45 seconds or less. The composition is preferablyapplied to the desired area that is dry or has been dried prior toapplication, or to which a basecoat has been previously applied.

According to a preferred embodiment of the present invention,compositions having improved cosmetic properties such as, for example,improved feel upon application (for example, texture, reduced drag ortackiness), and/or increased shine/color characteristics are provided.

According to other embodiments of the present invention, methods ofimproving the feel, shine and/or texture properties of a composition,comprising adding at least one oil-soluble polar modified polymer, atleast one sugar silicone surfactant and at least one polyol to thecomposition are provided. In accordance with this embodiment, the atleast one oil-soluble polar modified polymer, the at least one sugarsilicone surfactant and the at least one polyol are present in amountssufficient to achieve the desired result.

Unless otherwise indicated, all numbers expressing quantities ofingredients, reaction conditions, and so forth used in the specificationand claims are to be understood as being modified in all instances bythe term “about.” Accordingly, unless indicated to the contrary, thenumerical parameters set forth in the following specification andattached claims are approximations that may vary depending upon thedesired properties sought to be obtained by the present invention.

Notwithstanding that the numerical ranges and parameters setting forththe broad scope of the invention are approximations, the numericalvalues set forth in the specific examples are reported as precisely aspossible. Any numerical value, however, inherently contain certainerrors necessarily resulting from the standard deviation found in theirrespective measurements. The following examples are intended toillustrate the invention without limiting the scope as a result. Thepercentages are given on a weight basis.

Example 1 Mascara Composition

Phase Chemical Name Weight % A Propylparaben 0.20 A Isododecane Q.S. AOil-soluble polar modified polymer 10.00 A Iron Oxides 8.00 AHyperbranched Polyol 20.00 B DI Water 14.92 B Disodium EDTA 0.10 BPotassium Cetyl Phosphate 2.00 B Methylparaben 0.25 B Sugar SiliconeSurfactant 20.00 C Simethicone 0.10 D PHENOXYETHANOL (and) 1.10METHYLPARABEN (and) ISOPROPYLPARABEN (and) ISOBUTYLPARABEN (and)BUTYLPARABEN Total 100.00

Procedure

1. In a suitable size metal container, Hyperbranched Polyol, Oil-solublepolar modified polymer and Propylparaben were added and heated to 90 Cor until all solids have melted.

2. When all solids had melted, Isododecane was added to batch.

3. Iron Oxide was added and the batch was homogenized for at least 1 hr.

4. In side tank B with water bath, All Phase B was added and mixed untiluniform. Heated content to 90 C.

5 Mixed side tank B for 20 minutes.

6 When both tanks were at temperature, slowly added side tank B to maintank A while homogenizing at 850 rpm.

7 After 5 minutes of homogenizing, added Simethicone. Homogenize for 30minutes at 90 C.

8 Began cooling batch naturally to 25 C.

9 Continued cooling batch with planetarian blade to 25 C.

10 Added Phase D to main tank at 35 C. Continued cooling to 25 C.

11 Dropped batch at 25 C, and measured pH and viscosity.

Example 2 Lip Stick Composition

Phase Chemical Name Weight % A Polyglyceryl-2 Triisosterate 3.00 AOctyldodecyl Neopantanoate 11.68 A Hydrogenated Polydecene Q.S. AHyperbranched polyol 5.00 A Polyethylene 400 8.00 A Oil-soluble polarmodified polymer 7.00 A Tricaprylin 13.80 B Color pigments 5.00 B Mica2.00 C Deionized Water 17.50 C Glycerin 3.00 C Sugar silicone Surfactant10.00

Procedure

1. Phase A materials were added to a suitable size beaker A and heatedto 95 Celsius degrees.

2. When enough solids had melted, the contents were mixed with moderatespeed until all solids had melted at 95 Celsius degrees.

3. The temperature was slightly lowered to 85 Celsius degrees andpigments and mica were added.

4. The contents of main beaker A was transferred to a Silverson mixerfor emulsification while maintaining the temperature at 85-90 Celsiusdegrees.

5. In a separate beaker B, glycerin, and sugar silicone surfactant wereadded into DI water and mixed and heated to 85 Celsius degrees.

6. The contents of side beaker B was added dropwise into the beaker Awhile emulsifying at 9000 rpm under the Silverson mixer for 30 minutes.Afterward, the emulsification speed was lowered to 2000 rpm for 5minutes.

7. The contents were poured into lipstick molds at 80 Celsius degrees.

8. The lipstick in molds was placed in a cooling tunnel for 15 minutesat −10 Celsius degrees. Once cooled, the lipstick in molds were removedfrom the cooling tunnel to equilibrate to 25 Celsius degrees and removedfrom the molds after lipsticks had thawed to 25 Celsius degrees.

Example 3 Lip Gloss Composition

Phase Chemical Name Ex 3 A Polyglyceryl-2 Triisosterate 6.00 AOctyldodecyl Neopantanoate 3.43 A Hydrogenated Polydecene Q.S. AHyperbranched polyol 5.00 A Oil-soluble polar modified polymer 10.00 ATricaprylin 13.80 A Color pigments 5.00 A Mica 2.00 B Deionized Water35.00 B Glycerin 3.00 B Sugar silicone Surfactant 10.00

Procedure

1. Phase A materials were added to a suitable size beaker A and heatedto 95 Celsius degrees.

2. When enough solids had melted, the contents were mixed with moderatespeed until all solids had melted at 95 Celsius degrees.

3. The temperature was slightly lowered to 85 Celsius degrees andpigments and mica were added.

4. The contents of main beaker A was transferred to a Silverson mixerfor emulsification while maintaining the temperature at 85-90 Celsiusdegrees.

5. In a separate beaker B, glycerin and sugar silicone surfactant wereadded into DI water and mixed and heated to 85 Celsius degrees.

6. The contents of side beaker B was added dropwise into the beaker Awhile emulsifying at 9000 rpm under the Silverson mixer for 30 minutes.Afterward, the emulsification speed was lowered to 2000 rpm for 5minutes until contents were cooled to 25 Celsius degrees.

7. The contents of main beaker A was poured into container.

Example 4 Foundation Composition

INCL Name % isododecane 34.85 isohexadecane 2.25 Oil-soluble polarmodified 6.75 polymer (PP207*) polyglyceryl-2 triisostearate 2.5hyperbranched polyol 5 TITANIUM DIOXIDE 7.82 IRON OXIDES 2.18 DI Water22 cellulose 0.15 sugar silicone surfactant 15 DISODIUM EDTA 0.20propylene glycol 0.50 PHENOXY-2 ETHANOL 0.40 CHLORPHENESIN 0.20 ETHYLPARABEN 0.2 Total 100 *PP207 is a linear polypropylene-ethylene-maleicanhydride copolymer wax commercially available from Clariant under thetradename LICOCARE PP207 LP 3349.

Procedure

1. In container A, Oil-soluble polar modified polymer and hyperbranchedpolyol were melted in the isohexadecane and isododecane until fullydissolved. The temperature was brought to 900 C.

2. While maintaining the temperature, polyglyceryl-2 triisostearate,titanium dioxide, and iron oxides were added to container A until fullydissolved.

3. In a separate container B, water, cellulose, sugar siliconesurfactant, disodium EDTA, propylene glycol and preservatives were mixedand heated to 900 C.

4. The contents of container B were added to the contents of container Aslowly at high sheer (˜1000 rpm).

5. Heat was maintained at 700 C-800 C for 20 minutes while maintaininghigh sheer mixing.

6. The mixture was cooled to room temperature while mixing.

What is claimed is:
 1. A composition comprising: (a) water; (b) at leastone oil-soluble polar modified polymer consisting of polypropyleneand/or polyetheylene monomers, and maleic anhydride units, and having aweight-average molecular weight of less than or equal to 25 000 g/moland a melting point above 75° C.; (c) a surfactant system comprising atleast one sugar silicone surfactant; and (d) at least one hyperbranchedpolyol having at least two hydroxyl groups; wherein the composition isin the form of an emulsion.
 2. The composition of claim 1, furthercomprising at least one colorant.
 3. The composition of claim 1, whereinthe composition comprises water in an amount ranging from about 20% toabout 50% by weight with respect to the weight of the composition. 4.The composition of claim 1, wherein the composition is solid.
 5. Thecomposition of claim 1, wherein the composition is a mascara, a lipstickor a foundation.
 6. The composition of claim 1, further comprising atleast one gelling agent.
 7. The composition of claim 6, wherein thegelling agent is a cellulosic gelling agent.
 8. The composition of claim1, wherein the oil-soluble polar modified polymer is a polypropyleneand/or polyethylene homopolymer or copolymer modified with maleicanhydride units.
 9. The composition of claim 1, wherein thehyperbranched polyol is present in an amount ranging from about 0.1 toabout 15% by weight based on the total weight of the composition. 10.The composition of claim 1, wherein the weight ratio of hyperbranchedpolyol to oil-soluble polar modified polymer is between 3:1 and 1:3. 11.The composition of claim 1, wherein the weight-average molecular weightof the oil-soluble polar modified polymer is from 1000 to 22,000 g/mol.12. The composition of claim 1, wherein the melting point of theoil-soluble polar modified polymer is between 90° C. and 160° C.
 13. Thecomposition of claim 1, wherein the oil-soluble polar modified polymerhas from about 0.5% to about 10% maleic anhydride units by weight withrespect to the weight of the oil soluble polar modified polymer.
 14. Thecomposition of claim 1, wherein the oil-soluble polar modified polymerhas from about 1% to about 8% maleic anhydride units by weight withrespect to the weight of the oil soluble polar modified polymer.
 15. Thecomposition of claim 1, wherein the surfactant system consistsessentially of the at least one silicone sugar surfactant.